The stunning 36-year-old star stole the spotlight away from Brad Pitt at tonight's Critics' Choice Awards in New York City, though he was actually nominated for an award.
The In The Land of Milk & Honey director wowed in a tight-fitting leather skirt which managed to make her look both slim and elegant.
Hell for leather: Angelina Jolie and Brad Pitt arrive at the Critic's Choice Awards at Crimson in NYC tonight
She paired the ferocious piece with a simple white silk shirt, classic black heels and a chic black clutch.
Her only concessions to colour were the emeralds that shimmered at her throat and her ears.
The actress arrived hand-in-hand with the 48-year-old Pitt, who looked rather dapper himself in a two-piece blue suit, white shirt and black tie.
Perfection: The 36-year-old actress stuns in a leather skirt and emerald gemstones
The look of love: Angelina and Brad gaze into one another's eyes
His accessory of a cane was far less glamorous than Angelina's gorgeous gemstones, though far more necessary.
He is said to be recovering from a torn medial collateral ligament, an injury obtained by falling over on a ski slope last week.
He broke out the cane over the weekend at the 23rd Annual Palm Springs International Film Festival Awards Gala.
Winning! The 46-year-old actor looks dapper, especially with his cane
A united front: The couple walked down the red carpet holding hands
The actor told reporters he suffered an injury after falling over on a ski slope while holding onto one of the twins.
He was honoured at the ceremony with the Desert Palm Achievement Award which noted his acting skills in Moneyball and The Tree of Life.
Perhaps winning another award tonight will lessen the pain of his injury.
What a gentleman! Pitt helps Angie out of the car even though he's injured
What beauties! The A-list couple even have matching hair colours these days
He has been nominated for his work as former Oakland Athletics coach Billy Bean in the 2011 film Moneyball.
He is up against pal George Clooney, as well as Leonardo DiCaprio, Jean Dujardin, MIchael Fassbender and Ryan Gosling.
